40th International Conference on Production Engineering of Serbia
ICPES 2025
Nis, Serbia, 18-19th september 2025


HYDROGEN EMBRITTLEMENT OF RECYCLED PRESSURE VESSEL STEEL P460NL1

Tobias Walder, Fabian BOBNER, Thomas Staubmann, Hamdi Elsayed, Fernando Wachomicka, Rudolf Vallant

DOI: 10.46793/ICPES25.145W


Abstract:

Hydrogen embrittlement (HE) presents a critical challenge to the structural integrity of pressure vessels, especially those manufactured from recycled steel. This study explores the susceptibility of recycled P460 NL1 pressure vessel steel to hydrogen induced degradation. A comprehensive approach is employed, combining Slow Strain Rate Testing (SSRT) under electrochemical hydrogen charging, metallographic analysis, and Thermal Desorption Spectroscopy (TDS), to investigate the influence of microstructural characteristics on mechanical performance and hydrogen uptake. Both base metal and welded specimens are examined to assess the effects of welding on hydrogen behavior. Additionally, detailed microstructural investigations are carried out to evaluate the role of non-metallic inclusions, specifically their number, size, and morphology in the embrittlement mechanisms of both recycled and conventionally produced steels.This study aims to elucidate the relationship between hydrogen absorption, inclusions, and microstructural features in recycled steels, which are increasingly utilized in sustainable engineering applications. The findings are expected to enhance the understanding of embrittlement mechanisms in recycled steels and support the development of effective mitigation strategies against hydrogen-related failures

Keywords:

P460NL1, HE, Electrochemical hydrogen charging, SSRT, TDS

References:


[1] F. Umbach: The European Green Deal faces huge challenges; Energy Transition, February 10; 2020. https://www.gisreportsonline.com/r/european-green-deal/
[2] L. Yang et al.: Life cycle carbon footprint of electric arc furnace steelmaking processes under different smelting modes in China; Sustainable Materials and Technologies; Volume 35, April 2023. https://doi.org/10.1016/j.susmat.2022.e00564
[3] Vallourec Expands its Range of Qualified Materials for Hydrogen Service, 02/27/2023; https://www.vallourec.com/en/all-news/group-2023-qualified-materials-for-hydrogen-service
[4] Sandvik to acquire the tube engineering solutions company Gerling GmbH, 2021 https://www.home.sandvik/en/news-and-media/news/2021/11/sandvik-to-acquire-the-tube-engineering-solutions-company-gerling-gmbh/
[5] F. Passaro: A Green Future for Steel, Climate Bonds Initiative 2022; www.climatebonds.net
[6] M. Elboujdaini & R. W. Revie: Metallurgical factors in stress corrosion cracking (SCC) and hydrogen-induced cracking (HIC), J Solid State Electrochem 13:1091–1099 (2009); DOI 10.1007/s10008-009-0799-0
[7] Z. Szklarska-smialowska, E. Lunarska: The effect of sulfide inclusions on the susceptibility of steels to pitting, stress corrosion cracking and hydrogen embrittlement; Materials and Corrosion, Volume 32, Issue 11, 478-485 (1981); https://doi.org/10.1002/maco.19810321103
[8] N. Shikomba et al.: Resistance of welded low-alloyed pressure vessel and pipeline steels in gaseous hydrogen; Welding in the World, May 2025. https://doi.org/10.1007/s40194-025-02074-7
[9] A. Turnbull ed.: Proceedings of Conference Hydrogen Transport and Cracking in Metals, 1995; ISBN 0-901716-67-7; pp. 4, 130.
[ 0] G.T. Park, S.U. Koh, H.G. Jung, K.Y. Kim, Effect of microstructure on the hydrogen trapping efficiency and hydrogen induced cracking of linepipe steel, Corros. Sci. 50 (2008) 1865–1871, https://doi.org/10.1016/j.corsci.2008.03.007
[ 1] D. Brooksbank and K. W. Andrews: Production and application of clean steels, J. Iron Steel Inst., 210 (1972), 246.
[ 2] A. Hamed et al.: Assessing the hydrogen embrittlement susceptibility of an existing L360NB natural gas pipeline steel for 100 % hydrogen transport; Corrosion Science 244 (2025) 112648. https://doi.org/10.1016/j.corsci.2024.112648